Acta Crystallographica Section E (Dec 2009)

Imidazolium 4-aminobenzoate

  • Rommel B. Viana,
  • R. H. De Almeida Santos,
  • Denise Gilmour,
  • Alan R. Kennedy,
  • Rodolfo Moreno-Fuquen

DOI
https://doi.org/10.1107/S160053680904625X
Journal volume & issue
Vol. 65, no. 12
pp. o3044 – o3045

Abstract

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In the title salt, C3H5N2+·C7H6NO2−, the carboxylate group of the 4-aminobenzoate anion forms a dihedral angle of 13.23 (17)° with respect to the benzene ring. There are N—H...O hydrogen-bonding interactions between the anion and cation, and weak intermolecular C—H...O contacts with carboxylate O-atom acceptors of the 4-aminobenzoate anion result in extended three-dimensional R44(22) and R56(30) edge-fused rings along the [100], [010] and [001] directions.