Acta Crystallographica Section E (Sep 2013)

8-Hydroxyquinolin-1-ium hydrogen sulfate monohydrate

  • Maamar Damous,
  • George Dénès,
  • Sofiane Bouacida,
  • Meriem Hamlaoui,
  • Hocine Merazig,
  • Jean-Claude Daran

DOI
https://doi.org/10.1107/S1600536813022319
Journal volume & issue
Vol. 69, no. 9
pp. o1458 – o1459

Abstract

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In the crystal structure of the title salt hydrate, C9H8NO+·HSO4−·H2O, the quinoline N—H atoms are hydrogen bonded to the bisulfate anions. The bisulfate anions and water molecules are linked together by O—H...O hydrogen-bonding interactions. The cations and anions form separate layers alternating along the c axis, which are linked by N—H...O and O—H...O hydrogen bonds into a two-dimensional network parallel to (100). Further O—H...O contacts connect these layers, forming a three-dimensional network, in which two R44(12) rings and C22(13) infinite chains can be identified.