Materials (Jan 2023)

Improving the p-Type CuCrO<sub>2</sub> Thin Film’s Electrical and Optical Properties

  • Jiaxin Jiang,
  • Yu-Feng You,
  • Dhanapal Vasu,
  • Sheng-Chi Chen,
  • Te-Wei Chiu,
  • Gopi Prashanth,
  • Po Chou Chen

DOI
https://doi.org/10.3390/ma16031000
Journal volume & issue
Vol. 16, no. 3
p. 1000

Abstract

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In this research, we studied the functional properties of CuCrO2, which is the most promising p-type transparent conductive oxide (TCO). The thin films were fabricated using a spin coating technique. The diffraction patterns were obtained with the help of X-ray diffractions, and the optical properties of absorption characteristics were studied using UV-visible absorption. The physical properties of film formation and surface morphology were analyzed using FESEM analysis. The aging properties were also analyzed with the help of various precursors with different aging times. The CuCrO2 thin films’ functional properties were determined by using chelating agent and precursor solution aging times. The CuCrO2 thin films have better transmittance, resistance, figure of merit (FOM), and electrical conductivity. Moreover, the resistivity values of the CuCrO2 thin films are 7.01, 9.90, 12.54, 4.10, 2.42, and 0.35 Ω cm. The current research article covers the preparation of copper chromium delafossite thin films. These thin films can be suitable for hole transport layers in transparent optoelectronic devices.

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