Nanomaterials (Dec 2022)

Photodynamics of Bright Subnanosecond Emission from Pure Single-Photon Sources in Hexagonal Boron Nitride

  • Alexander V. Gritsienko,
  • Aliaksandr Duleba,
  • Mikhail V. Pugachev,
  • Nikita S. Kurochkin,
  • Igor I. Vlasov,
  • Alexei G. Vitukhnovsky,
  • Alexandr Yu. Kuntsevich

DOI
https://doi.org/10.3390/nano12244495
Journal volume & issue
Vol. 12, no. 24
p. 4495

Abstract

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Bright and stable emitters of single indistinguishable photons are crucial for quantum technologies. The origin of the promising bright emitters recently observed in hexagonal boron nitride (hBN) still remains unclear. This study reports pure single-photon sources in multi-layered hBN at room temperature that demonstrate high emission rates. The quantum emitters are introduced with argon beam treatment and air annealing of mechanically exfoliated hBN flakes with thicknesses of 5–100 nm. Spectral and time-resolved measurements reveal the emitters have more than 1 GHz of excited-to-ground state transition rate. The observed photoswitching between dark and bright states indicates the strong sensitivity of the emitter to the electrostatic environment and the importance of the indirect excitation for the photodynamics.

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