Characterization and carbon monoxide oxidation activity of La1.ySryCr1.xRuxO3 perovskites

Abstract

The oxidation of CO over La1-y Sr y Cr1-xRuxO3 perovskite type oxides with y=0.3 and 0 £x £0.100 have been studied. X-ray fluorescence analysis confirmed that content of elements in the bulk corresponds to the established nominal perovskite stoichiometry, indicating that no significant oxidation of ruthenium into volatile polyvalent oxides with their consequented escape from the sample occurred in air up to the temperature of 1000ºC. According to X-ray diffraction analysis, all sampls achieved the perovskite hexagonal with the presence of some SrCrO4. X-ray photoelectron spectroscopy analysis of ruthenium samples shows higher Ru and Sr surface concentrations than in the bulk. The binding energy for Ru3p is virtually the same in all samples and consistent with that of Ru 4+ (463.6.464.3eV). Kinetic studies were performed in a differential recycle reactor with a recycling ratio 80. The results show that substitution of Ru 4+ for Cr 3+ in La1-y Sr y CrO3 leads to a significant increase in both the activity and the activation energy. The global CO oxidation rate, referred on the BET surface area, correlates with the surface Ru 4+ atomic concentration. Hence, the activity reflect the surface enrichment in ruthenium. Moreover, an identical apparent activation energy E = 93 kJ/mol and the same specific rate per ruthenium surface ion were obtained for samples with a Ru content x ‡ 0.05 suggest that exposed Ru 4+ ions mainly participate in the reaction.

Keywords

• perovskite
• ruthenium
• co oxidation