Fabrication of Polarization Grating on <i>N</i>-Benzylideneaniline Polymer Liquid Crystal and Control of Diffraction Beam

Abstract

Photoresponsive photoalignable liquid crystalline polymers composed of phenyl benzoate terminated with N-benzylideneaniline were evaluated. These polymers are capable of axis-selective photoreaction, photoinduced orientation, and surface relief grating formation. Polarization holography using an He-Cd laser beam at a wavelength of 325 nm demonstrated the formation of a surface relief grating with a molecularly oriented structure based on periodic light-induced reorientation and molecular motion. Electrical switching of diffracted light using an electric field response of twisted-nematic cell containing a low-molecular-weight liquid crystal in combination was also demonstrated.

Keywords

• liquid crystalline polymer
• axis-selective photoreaction
• holography
• beam diffraction