Crystal structure and Hirshfeld surface analysis of 4-methyl-N-[2-(5-methylfuran-2-yl)phenyl]-N-[(5-phenylfuran-2-yl)methyl]benzenesulfonamide

Abstract

In the title compound, C29H25NO4S, the molecular conformation is stable with intramolecular C—H...O and C—H...N interactions being observed. In the crystal, molecules are linked by C—H...O interactions, forming layers parallel to the (100) plane. In addition, π–π [centroid-to-centroid distance = 3.4961 (7) Å] and C—H...π interactions connect the molecules within the layers. The layers are also bound to each other by van der Waals interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H...H (53.2%), C...H/H...C (28.9%) and O...H/H...O (13.8%) contacts.

Keywords

• crystal structure
• hydrogen bond
• van der waals interactions
• hirshfeld surface analysis