Boosting electrocatalytic performance via electronic structure regulation for acidic oxygen evolution

Qian Wu; Qingping Gao; Xingpeng Wang; Yuping Qi; Li Shen; Xishi Tai; Fan Yang; Xun He; Yan Wang; Yongchao Yao; Yuchun Ren; Yonglan Luo; Shengjun Sun; Dongdong Zheng; Qian Liu; Sulaiman Alfaifi; Xuping Sun; Bo Tang

iScience (Jan 2024)

Boosting electrocatalytic performance via electronic structure regulation for acidic oxygen evolution

Qian Wu,
Qingping Gao,
Xingpeng Wang,
Yuping Qi,
Li Shen,
Xishi Tai,
Fan Yang,
Xun He,
Yan Wang,
Yongchao Yao,
Yuchun Ren,
Yonglan Luo,
Shengjun Sun,
Dongdong Zheng,
Qian Liu,
Sulaiman Alfaifi,
Xuping Sun,
Bo Tang

Affiliations

Qian Wu: Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China; Corresponding author
Qingping Gao: Department of Chemical Engineering, Weifang Vocational College, Weifang 262737, Shandong, China
Xingpeng Wang: Department of Chemical Engineering, Weifang Vocational College, Weifang 262737, Shandong, China
Yuping Qi: Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China
Li Shen: Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China
Xishi Tai: Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China
Fan Yang: Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, Shandong, China
Xun He: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China
Yan Wang: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China
Yongchao Yao: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China
Yuchun Ren: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China
Yonglan Luo: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China
Shengjun Sun: College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, Shandong, China
Dongdong Zheng: College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, Shandong, China
Qian Liu: Institute for Advanced Study, Chengdu University, Chengdu 610068, Sichuan, China
Sulaiman Alfaifi: Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
Xuping Sun: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, Sichuan, China; College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, Shandong, China; Corresponding author
Bo Tang: College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, Shandong, China; Laoshan Laboratory, Qingdao 266237, Shandong, China; Corresponding author

Journal volume & issue: Vol. 27, no. 1
p. 108738

Abstract

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Summary: High-purity hydrogen produced by water electrolysis has become a sustainable energy carrier. Due to the corrosive environments and strong oxidizing working conditions, the main challenge faced by acidic water oxidation is the decrease in the activity and stability of anodic electrocatalysts. To address this issue, efficient strategies have been developed to design electrocatalysts toward acidic OER with excellent intrinsic performance. Electronic structure modification achieved through defect engineering, doping, alloying, atomic arrangement, surface reconstruction, and constructing metal-support interactions provides an effective means to boost OER. Based on introducing OER mechanism commonly present in acidic environments, this review comprehensively summarizes the effective strategies for regulating the electronic structure to boost the activity and stability of catalytic materials. Finally, several promising research directions are discussed to inspire the design and synthesis of high-performance acidic OER electrocatalysts.

Published in iScience

ISSN: 2589-0042 (Online)
Publisher: Elsevier
Country of publisher: United States
LCC subjects: Science
Website: http://www.cell.com/iscience/home

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