Experimental data for green synthesis of Zn-abietate complex from natural resin
Jamille S. Correa,
Júlia O. Primo,
Carla Bittencourt,
Dienifer F.L. Horsth,
Eduardo Radovanovic,
Alceu T. Silveira-Jr,
Henrique E. Toma,
Cristina M. Zanette,
Fauze J. Anaissi
Affiliations
Jamille S. Correa
Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil
Júlia O. Primo
Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil
Carla Bittencourt
Department of Chemistry, University of Mons, Place du Parc 23, Mons 7000, Belgium
Dienifer F.L. Horsth
Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil
Eduardo Radovanovic
Department of Chemistry, Universidade Estadual de Maringá, UEM, Av. Colombo 5790, Maringá, PR 87020-900, Brazil
Alceu T. Silveira-Jr
Institute of Chemistry, University of Sao Paulo, São Paulo, SP 05508.000, Brazil
Henrique E. Toma
Institute of Chemistry, University of Sao Paulo, São Paulo, SP 05508.000, Brazil
Cristina M. Zanette
Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil
Fauze J. Anaissi
Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil; Corresponding author.
This data article is associated with the work “Ecofriendly synthesis of Zn-abietate complex derived from Pinus elliottii resin and its application as an antibacterial pigment against S. aureus and E. coli”. The characterization data of the Zn-abietate complex obtained from Pinus elliottii resin and their reactional intermediary (Na-abietate) are reported. The Na-abietate was prepared with purified Pinus resin and sodium hydroxide (≥ 99%) in a stoichiometric ratio of 1:1. For the Zn-abietate synthesis was used ZnSO4 and Na-abietate solutions were at mild temperature and stirring without using organic solvents to ensuring the green character of the synthesis. Spectroscopic and structural characterization was consistent with an octahedral complex involving three carboxylate ligands per metal ion. X-ray photoelectron spectroscopy (XPS) analysis of the Na-abietate salt confirms the presence of carbonyl groups, carbon-oxygen atoms simple bonds (O-C/O=C), and carboxylate groups oxygen atoms (O-C=O). Analysis of the Zn LMM Auger, for the Zn-abietate complex, indicates the presence of zinc atoms with oxidation state Zn2+, this is supported by the distance between Zn 2p3/2 and 1p1/2 in the XPS spectrum. Together, these data will be useful for the structural representation of the samples.
