Acta Crystallographica Section E (Dec 2012)

[5-(Pyridin-2-yl)-1H-tetrazole-κ2N4,N5]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate

  • Lei Lu,
  • Ping Yang,
  • Bing Li,
  • Lin-Fang Shi,
  • Hua-Ru Cao

DOI
https://doi.org/10.1107/S1600536812047605
Journal volume & issue
Vol. 68, no. 12
pp. m1527 – m1527

Abstract

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In the title CuI compound, [Cu(C6H5N5)(C18H15P)2]BF4, the CuI cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetrazole ligand and coordinated by two triphenylphosphane ligands in a distorted tetrahedral geometry. The tetrazole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetrafluoridoborate anion links to the complex cation via an N—H...F hydrogen bond.