Acta Crystallographica Section E (Mar 2014)

2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate

  • Evgeny Bulatov,
  • Dina Boyarskaya,
  • Tatiana Chulkova,
  • Matti Haukka

DOI
https://doi.org/10.1107/S1600536814002372
Journal volume & issue
Vol. 70, no. 3
pp. o260 – o260

Abstract

Read online

In the title compound, C16H11NO2·C5H9NO, the dihedral angles between the maleimide and phenyl rings are 34.7 (2) and 64.8 (2)°. In the crystal, the 2,3-diphenylmaleimide and 1-methylpyrrolidin-2-one molecules form centrosymmetrical dimers via pairs of strong N—H...O hydrogen bonds and π–π stacking interactions between the two neighboring maleimide rings [centroid–centroid distance = 3.495 (2) Å]. The dimers are further linked by weak C—H...O and C—H...π hydrogen bonds into a three-dimensional framework.