Towards Balanced Strength and Plasticity in Graphene-Nickel Composites: The Role of Graphene, Bimodal Metal Powder and Processing Conditions

Abstract

Due to their higher strength and lighter weight compared to conventional metals, graphene-nickel (Gr-Ni) composites have recently gained growing interest for use in the automotive and aerospace industries. Homogeneous Gr dispersion, the metal powder dispersity and processing conditions play a key role in obtaining the desired grain size distribution, an amount of high angle grain boundaries thus reaching the desired balance between strength and plasticity of the composite. Here, we report an approach to fabricating graphene-nickel composites with balanced strength and ductility through the microstructure optimization of the nickel matrix. A graphite platelets (GP) content of 0.1–1 wt.% was used for the optimization of the mechanical properties of the material. In situ, conversion GP-to-Gr was performed during the milling step. This paper discusses the effect of bimodal nano- and micro-sized Ni (nNi and mNi) on the mechanical properties and microstructure of Gr-Ni composites synthesized using a modified powder metallurgy approach. Specimens with varied nNi:mNi ratios were produced by two-step compaction and investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, electron back-scattered diffraction (EBSD) and nanoindentation. The best combination of ultimate tensile strength (UTS), yield limit (YL), elongation and hardness were obtained for 100nNi and 50nNi matrices, and the best composites were those with 0.1% graphene. The addition of more than 0.5 wt.% GP to the nickel matrix induces the fracture mechanism change from tensile to brittle fracture. Dedicated to the 300th anniversary of the St. Petersburg University Foundation.

Keywords

• nickel-matrix composites
• graphene
• bimodal precursor powder
• ultimate tensile strength
• yield limit
• elongation