Dry Reforming of Methane Using Ni Catalyst Supported on ZrO₂: The Effect of Different Sources of Zirconia

Abstract

Dry reforming of methane (DRM) has a substantial potential to provide a cost-effective process and in reducing greenhouse gases. Its application has been hindered by carbon deposition and instability problems. The use of an appropriate catalyst is influenced by the support type. The objective of this investigation is to elucidate the effect of different sources of ZrO2 support. Four kinds of ZrO2, namely RC-100 and Z-3215, MKnano, and ELTN were acquired from Japan, Canada, and China, respectively. The catalyst samples were analyzed by BET, XRD, TPR, TPD, TEM, TGA, TPO, FT-IR, and Raman. The analysis of the structural properties displayed that all Ni-supported catalysts, regardless of their source, are mesoporous and that 5Ni-RC-100 possessed the highest BET surface area of 17.7 m2/g and 5Ni-MKnano had the lowest value of BET 3.16 m2/g. In the TPD and TEM analysis, the 5Ni-RC-100 catalyst presented the highest intensity of basicity and the minimum average particle size of 3.35 nm, respectively. The 5Ni-RC-100 catalyst outperformed 5Ni-ELTN by exhibiting 44% higher CH4 conversion; however, 5Ni-RC-100 gave the highest weight loss in the TGA analysis of 66%.

Keywords

• coke
• CO₂ reforming of CH₄
• different sources of zirconia support
• Ni catalyst