Acta Crystallographica Section E (Jun 2011)

3-(Piperidin-1-ium-1-yl)-6-azoniaspiro[5.5]undecane dibromide monohydrate

  • Jorge Gonzalez,
  • Roberto Atilano-Coral,
  • Ana Lilia Peraza-Campos,
  • David Ortegón-Reyna,
  • Eleuterio Álvarez

DOI
https://doi.org/10.1107/S1600536811008713
Journal volume & issue
Vol. 67, no. 6
pp. o1308 – o1309

Abstract

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The title compound, C15H30N22+·2Br−·H2O, was synthesized by reaction of 4-piperidinopiperidine with dibromopentane. The dication is built up from three linked piperidine rings, two of which have one quaternary N atom in common (azoniaspiro), whereas the third is N—C bonded to the azoniaspiro system and protonated on the N atom (piperidinium). All three piperidine rings adopt chair conformations. The crystal structure features O—H...Br and N—H...Br hydrogen bonds.