Advanced Science (Dec 2022)

Texture Regulation of Metal–Organic Frameworks, Microwave Absorption Mechanism‐Oriented Structural Optimization and Design Perspectives

  • Zhenguo Gao,
  • Aamir Iqbal,
  • Tufail Hassan,
  • Limin Zhang,
  • Hongjing Wu,
  • Chong Min Koo

DOI
https://doi.org/10.1002/advs.202204151
Journal volume & issue
Vol. 9, no. 35
pp. n/a – n/a

Abstract

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Abstract Texture regulation of metal–organic frameworks (MOFs) is essential for controlling their electromagnetic wave (EMW) absorption properties. This review systematically summarizes the recent advancements in texture regulation strategies for MOFs, including etching and exchange of central ions, etching and exchange of ligands, chemically induced self‐assembly, and MOF‐on‐MOF heterostructure design. Additionally, the EMW absorption mechanisms in approaches based on structure–function dependencies, including nano‐micro topological engineering, defect engineering, interface engineering, and hybrid engineering, are comprehensively explored. Finally, current challenges and future research orientation are proposed. This review aims to provide new perspectives for designing MOF‐derived EMW‐absorption materials to achieve essential breakthroughs in mechanistic investigations in this promising field.

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