Pr³⁺-Doped Lithium Niobate and Sodium Niobate with Persistent Luminescence and Mechano-Luminescence Properties

Abstract

In this research, a comprehensive series of Pr3+-doped lithium niobate and sodium niobate materials were obtained at different temperatures via solid-state sintering, and their structures and properties were compared. NaNbO3: 0.75% Pr3+ phosphors were synthesized by sintering at 1150 °C for 2 h and emitted red persistent luminescence for more than 1200 s, peaking at 612 nm under UV excitation, which was a typical long persistent luminescence phenomenon. Furthermore, the sample glowed when pressurized, and a red bright luminescence which lasted for several seconds was visible to the naked eye. This was a typical mechanical luminescence phenomenon of samples under mechanical stress, directly converting mechanical energy into light energy. It was determined that NaNbO3:Pr3+ and LiNbO3:Pr3+ both possess multimode luminescence. Owing to their red long persistent luminescence (LPL) and mechano-luminescence (ML) properties, Pr3+ phosphors can be employed in fields, such as display technologies, stress sensing, structural damage detection, and other complex applications.

Keywords

• phosphors
• red persistent luminescence
• multimodal luminescence