Investigation of the structural, morphological, and magnetic properties of small crystalline Co–Cu ferrite nanoparticles in the single-domain regime

Abstract

Single-domain Co0.5Cu0.5Fe2O4 ferrite nanoparticles with a crystallite size of 23 nm were hydrothermally prepared and characterized using x-ray diffraction, transmission electron microscopy, Fourier-transform infrared (FT-IR) spectroscopy, and vibrating sample magnetometry. According to the Rietveld refinement results, the prepared nanoparticles were single-phase with spinel type structures. The transmission electron microscope measurements demonstrated that the nanoparticles were spherical in shape. The FT-IR spectrum showed two principle absorption bands, confirming the characteristic features of cubic spinel ferrites. Magnetization data revealed that the prepared nanoparticles were ferrimagnetic from room temperature to 10 K, with well-defined saturation magnetization, coercivity, and remanence magnetization. The remanence magnetization and coercivity were found to increase with decreasing temperature. The value of room temperature squareness ratio (Mr/Ms) of 0.42 was found to be somewhat similar to that expected (0.5) for a system of noninteracting single-domain nanoparticles, suggesting that the prepared nanoparticles are in a single-domain regime. The temperature dependence of coercivity was found to have slight deviations from Kneller’s law, possibly due to interactions between nanoparticles. The zero field cooled–field cooled curves indicated that below 150 K, the nanoparticles were ferrimagnetic dressed with spin-glass behavior, resulting from interactions between the ferrimagnetic nanoparticles and/or random freezing of surface spins.