Third order nonlinearity examined by pulsed and CW lasers: an organic urea barbituric acid (UBA) single crystal for optical limiting application with DFT study

Abstract

Bulk size of urea barbituric acid single crystal which has not been reported earlier was successfully grown by slow evaporation solution growth method. Single-crystal XRD brought out the lattice constant and the crystal system is observed to be monoclinic with space group P. Functional group of UBA were determined by FT-IR. UBA crystal is entirely visible from 270 to 900 nm with linear optical energy gap value to be 4.50 eV. The observed HOMO–LUMO energy gap was 5.21 eV. Thermally, UBA crystal is found to be stable up to 184˚°C. The C _p value of UBA increases from 1.21 to 1.58 J g ^−1 K ^−1 with the temperature difference from 30 to 100˚°C. UBA shows good photoconductive nature and it found to be positive and Laser Damage Threshold (LDT) value of UBA crystal is 0.97 GW cm ^−2 . Hardness testing confirms that UBA crystal belongs to soft nature category. Dielectric properties of UBA crystal are studied as a function of frequency and temperature. Third order NLO properties of the UBA crystal were studied under CW and pulsed lasers (ns) regimes using Z-scan technique. Good Optical limiting (OL) response (2.2860 х 10 ^12 W/m ^2 ) confirms the efficiency of UBA crystal to be used as optical limiters for protection towards short pulse lasers.

Keywords

• Urea barbituric acid (UBA) single crystal
• Single-crystal XRD
• TG-DTA
• Photoconductivity
• LDT
• Z-scan