Directionally solidified NiCoCrFeAlW eutectic high-entropy alloy: Microstructure and mechanical properties

Abstract

The NiCoCrFeAlW eutectic high-entropy alloy exhibits a balanced combination of ductility and strength. This study examines the microstructure evolution and mechanical properties of the Ni30Co30Cr10Fe10Al18W2 alloy at varying growth velocities (10, 20, 50, 100, and 200 μm/s), which in its as-cast state, features a microstructure that includes both coarse dendrites and lamellar eutectic. The structure of the coarse dendrites is characterized by an ordered body-centered cubic (B2) phase, while the lamellar eutectic, features a combination of face-centered cubic (FCC) and ordered B2 phases. The microstructure, characterized by lamellar and dendritic structures that are parallel to the growth direction after directional solidification, undergoes a morphological transition at the solid-liquid interface from a planar to a dendritic form as growth velocity increases. The tensile fracture strength initially increases with the growth velocity, reaching a peak of 1286 MPa at a velocity of 50 μm/s, and then subsequently decreases as the growth velocity continues to increase. Directional solidification results in an increase in sample elongation with increasing growth velocity, achieving an elongation of 22.5% at 200 μm/s. An examination of the deformation mechanism reveals that the lamellar structure, composed of the more ductile FCC phase and the harder B2 phase, effectively harmonizes the plasticity and strength of the alloy. Therefore, directional solidification significantly adjusts the eutectic microstructure's orientation, thereby enhancing the mechanical properties along the direction of solidification.

Keywords

• Eutectic high-entropy alloy
• Directional solidification
• Phase formation analysis
• Microstructure evolution
• Mechanical properties