Vermicompost as a natural adsorbent material: characterization and potentialities for cadmium adsorption

Abstract

Vermicompost (humic material) samples were submitted to characterization by infrared spectroscopy, X-ray diffractometry, thermogravimetric analysis, electron microscopy etc. In addition, its cation exchange capacity (CEC) was determined. Factorial experiments were designed in order to elucidate the interaction mechanisms between Cd2+ and the adsorptive sites of vermicompost. The maximum adsorptive capacity for cadmium was evaluated by a Langmuir isotherm. The characterization revealed that vermicompost exhibits high CEC values (ca. 72.9 meq per 100 g), high surface area (porous material), chelating groups and a maximum adsorptive capacity for Cd (38.6 mg g-1) at pH 5.0. This potential application was exploited in the analysis of synthetic and real (mineral water) samples with Cd concentrations of ca 5 mug L-1, requiring a preconcentration step. An enrichment factor of 100 was attained.

Keywords

• vermicompost
• characterization
• cadmium adsorption