Enhanced CuAl₂O₄ Catalytic Activity via Alkalinization Treatment toward High CO₂ Conversion during Reverse Water Gas Shift Reaction

Abstract

CO2 catalytic conversion to CO would likely be an important part of CO2 mitigation and utilization. In this work, CuAl2O4 was developed with a spinel structure that acts as an active and stable catalyst for this reaction. Here, the fundamental characteristics of CuAl2O4 catalyst were studied to understand the catalytic mechanism for the Reverse Water Gas Shift reaction. Based on the catalytic mechanism, the CuAl2O4 catalyst was found to have exceptional catalytic activity due to the high dispersion of copper on its surface, and it could have higher catalytic activity by increasing the oxygen vacancies on the surface of the catalyst via alkalinization treatment. By combining with XPS spectra, the relationship between the Raman mode and the oxygen vacancy structure on the CuAl2O4 surface was proved. Through these studies, it was proved that alkalinization treatment can regulate the oxygen vacancies on the surface of the catalyst and thus enhance the catalytic activity.

Keywords

• CuAl₂O₄
• Reverse Water Gas Shift (RWGS)
• oxygen vacancy
• alkalinization treatment