Electric Energy Storage Effect in Hydrated ZrO<sub>2</sub>-Nanostructured System
Alexander S. Doroshkevich,
Andriy I. Lyubchyk,
Boris L. Oksengendler,
Tatyana Yu. Zelenyak,
Nurbol O. Appazov,
Andriy K. Kirillov,
Tatyana A. Vasilenko,
Alisa A. Tatarinova,
Oksana O. Gorban,
Viktor I. Bodnarchuk,
Nadejda N. Nikiforova,
Maria Balasoiu,
Diana M. Mardare,
Carmen Mita,
Dorin Luca,
Matlab N. Mirzayev,
Asif A. Nabiyev,
Evgeni P. Popov,
Anca Stanculescu,
Tatyana E. Konstantinova,
Yulia V. Aleksiayenak
Affiliations
Alexander S. Doroshkevich
Donetsk Institute for Physics and Engineering Named after O.O. Galkin, 03028 Kyiv, Ukraine
Andriy I. Lyubchyk
Nanotechcenter LLC, Krzhizhanovsky str. 3, 03680 Kyiv, Ukraine
Boris L. Oksengendler
Ion-Plasma and Laser Technologies Institute after U. Arifov, Tashkent 100125, Uzbekistan
Tatyana Yu. Zelenyak
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Nurbol O. Appazov
I. Zhakhaev Kazakh Scientific Research Institute of Rice Growing, Abay Avenue 25B, Kyzylorda 120008, Kazakhstan
Andriy K. Kirillov
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Tatyana A. Vasilenko
Saint-Petersburg Mining University, 199106 St. Petersburg, Russia
Alisa A. Tatarinova
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Oksana O. Gorban
Donetsk Institute for Physics and Engineering Named after O.O. Galkin, 03028 Kyiv, Ukraine
Viktor I. Bodnarchuk
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Nadejda N. Nikiforova
Ion-Plasma and Laser Technologies Institute after U. Arifov, Tashkent 100125, Uzbekistan
Maria Balasoiu
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Diana M. Mardare
Faculty of Physics, “Alexandru Ioan Cuza” University of Iasi, Bld. Carol I, No. 11, 700506 Iasi, Romania
Carmen Mita
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi, Bld. Carol I, No. 11, 700506 Iasi, Romania
Dorin Luca
Faculty of Materials Science and Engineering, “Gheorghe Asachi” Technical University of Iasi (TUIASI), bd. Dimitrie Mangeron, nr. 41, 700050 Iasi, Romania
Matlab N. Mirzayev
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Asif A. Nabiyev
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Evgeni P. Popov
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
Anca Stanculescu
Optical Processes in Nanostructured Materials Laboratory, National Institute of Materials Physics, 405A Atomistilor Street, P.O. Box MG-7, 077125 Magurele, Romania
Tatyana E. Konstantinova
Donetsk Institute for Physics and Engineering Named after O.O. Galkin, 03028 Kyiv, Ukraine
Yulia V. Aleksiayenak
Joint Institute for Nuclear Research, Joliot-Curie 6, Dubna, 141980 Moscow, Russia
The dimensional effect of electric charge storage with a density of up to 270 μF/g by the hydrated ZrO2-nanoparticles system was determined. It was found that the place of localization of different charge carriers is the generalized heterophase boundary-nanoparticles surface. The supposed mechanism of the effect was investigated using the theory of dispersed systems, the band theory, and the theory of contact phenomena in semiconductors, which consists of the formation of localized electronic states in the nanoparticle material due to donor–acceptor interaction with the adsorption ionic atmosphere. The effect is relevant for modern nanoelectronics, microsystem technology, and printed electronics because it allows overcoming the basic physical restrictions on the size, temperature, and operation frequency of the device, caused by leakage currents.
