Preparation and characterization of cornstalk microspheric hydrochar and adsorption mechanism of mesotrione

Abstract

In this study, cornstalk was pyrolysed to obtain hydrochar (HC), which was used to remove mesotrione from aqueous solutions. HC characterization and batch experiments were conducted to investigate mesotrione adsorption and the underlying mechanism. The characterization revealed microspheres on the HC surface. FT-IR spectra showed that the HC contained a large number of –OH groups, C=C bonds of aromatic rings, C–H groups in aromatic rings and phenolic C–O bonds. The adsorption results showed that the mesotrione adsorption ability gradually increased as the HC preparation temperature increased. The quasi-second-order kinetic equation (R2 ≥ 0.9860, p < 0.05) agreed well with the mesotrione adsorption process. The maximum monolayer adsorption capacity, which was obtained at pH 7 and 45°C with HC prepared at 240°C, was 3181.7 mg kg−1 with the Langmuir isotherm model (R2 ≥ 0.9491, p < 0.05). Van der Waals and dipole forces and hydrogen bonds were inferred as the main adsorption mechanisms. HC has potential as an effective and energy-saving adsorbent for mesotrione to reduce environmental pollution.

Keywords

• hydrochar
• cornstalk
• mesotrione removal
• adsorption