Sn–Sc microalloying-induced property improvement and micromechanisms of an Al–Mg–Si alloy

Abstract

Microalloying is of great importance for the property modulation of lightweight high-strength aluminum alloys. Little is known, however, about the properties and micromechanisms of Al–Mg–Si alloys microalloyed with Sn and Sc. In this work, the property changes of Al–0.5Mg–0.4Si (wt%) alloys induced by 0.1Sn and 0.1Sn–0.1Sc (wt%) additions and underlying alloying mechanisms are revealed by atomic-scale transmission electron microscopy and first-principles calculations. The results show that the Sn–Sc coaddition results in a decreased diameter and an increased number density of the Sc-containing constituent particles of Mg2Si and Mg2(Si,Sn), as compared to the sole Sn addition. The featured Si-site columns in β'', B′ and β′ structures can be occupied by Sn and Sc. Substantial peak-aging β'' needles with confined cross-sectional coarsening are observed for the Sn–Sc containing alloy compared to the Sn containing alloy. The modified constituent particles and precipitates improve the plasticity and strength of peak-aging Al–Mg–Si–Sn–Sc alloy. The elevated peak-aging corrosion resistance and over-aging thermal stability of Al–Mg–Si–Sn–Sc alloy are associated with the sparse Sc-containing Mg2(Si,Sn) grain boundary precipitates and low strain filed of Al matrix around the β′ containing Sn/Sc, respectively. The obtained results are hoped to guide the design of high-performance Al alloys.

Keywords

• Al alloys
• Micro-alloying
• Microstructure
• Properties
• Atomic mechanism