Highly defective HKUST-1 with excellent stability and SO2 uptake: The hydrophobic armor effect of functionalized ionic liquids

Abstract

Water stability is one of the most important factors restricting the practical application of metal organic frameworks (MOFs). In this work, we fabricate a highly defective HKUST-1 framework with a mixed valence of CuI/CuII by mechanical ball milling method. This defective HKUST-1 is embellished by functionalized ionic liquids as hydrophobic armor, making the hybrid HIL1@HKUST-1 exhibits outstanding water stability, remarkable SO2 adsorption (up to 5.71 mmol g−1), and record-breaking selectivity (1070 for SO2/CO2 and 31,515 for SO2/N2) at 25 °C and 0.1 bar, even in wet conditions.

Keywords

• Metal organic frameworks
• SO2 adsorption
• Water stability
• Mechanochemistry
• Ionic liquids