Nature Communications (May 2017)

Synthesis of spiro quasi[1]catenanes and quasi[1]rotaxanes via a templated backfolding strategy

  • Luuk Steemers,
  • Martin J. Wanner,
  • Martin Lutz,
  • Henk Hiemstra,
  • Jan H. van Maarseveen

DOI
https://doi.org/10.1038/ncomms15392
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 7

Abstract

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Spiro compounds contain two or more rings linked together through one common atom. Here the authors provide a method to backfold both rings, producing spiro quasi[1]catenanes, via a strategy of temporarily linking the linear intermediates with covalent bonds.