Minerals (Jul 2024)
Lacustrine Environmental Perturbations during the Early Jurassic in the Qiangtang Basin, Northern Tibet
Abstract
The Early Jurassic was primarily a greenhouse phase in Earth’s history. Previous studies have predominantly focused on marine strata in the Tethyan Ocean, but continental records outside of Europe are still poorly understood, which has hindered a thorough understanding of its climate dynamics. To address this gap, organic, inorganic, and isotope geochemical analyses, along with mineralogical and sedimentological assessments, were conducted on samples from the Quemo Co Formation of well QZ-16 in the Qiangtang Basin (Eastern Tethys). This study aimed to investigate carbon cycle perturbations and consequences of redox conditions and paleosalinity within a lacustrine system during the Early Jurassic. The carbon isotope profile of well QZ-16 exhibited a long-term negative excursion of ca. −3.83‰ in lacustrine sediments, with relatively heavy δ13Corg values and small excursion magnitudes. Enhanced terrigenous input, as indicated by detrital proxies such as Si/Al, Ti/Al, and Zr/Al, was driven by accelerated continental weathering during the carbon isotope excursions. The presence of coarse-grained, pelitic siltstone deposits coincided with the onset of these negative carbon isotope excursions. Sr/Ba ratios (0.05–3.64, avg. 0.73) suggest a brackish to freshwater salinity regime within the third member, implying that the deposition of the Quemo Co Formation was influenced by both freshwater and seawater inputs. Most enrichment factors (VEF, ZnEF, NiEF) having a value below 1.0 and Corg/P ratios less than 50 indicate that the lacustrine environment was characterized by predominantly oxidizing conditions, particularly during the early Toarcian negative carbon isotope excursion (T-NCIE). Despite the record of the T-NCIE event, enhanced respiration in bottom and pore waters indicates that the Toarcian Oceanic Anoxic Event (T-OAE) was absent in this part of the eastern Tethys Ocean. The recorded Early Jurassic environmental settings in the Qiangtang Basin lacustrine system exhibit a close association with the T-CIE event (183 Ma), providing insights into the complex interplay between carbon cycle perturbation, climate, weathering, and biological processes during this greenhouse period.
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