Diffusion in periclase by combination of analytical formulas and thermodynamic model

Abstract

Analytical formulas for the temperature dependence of elastic constants of MgO combined with a thermodynamic model, which interconnects bulk properties to point defect parameters, can successfully reproduce the self diffusion coefficients of periclase at temperatures representative of the Earth's mantle conditions. <br><br> Although the calculated diffusion coefficients are estimated from a single measurement and cover a broad range of values (i.e. five orders of magnitude), an almost excellent agreement with the experimental ones is observed. The slight discrepancy at the highest temperature lies at error margins.