Тонкие химические технологии (Oct 2016)

CATALYSTS FOR ANODE OXIDATION OF FORMIC ACID ON CARBON NANOTUBES "TAUNIT"

  • N. A. Yashtulov,
  • M. V. Lebedeva,
  • S. M. Pestov

DOI
https://doi.org/10.32362/2410-6593-2016-11-5-51-56
Journal volume & issue
Vol. 11, no. 5
pp. 51 – 56

Abstract

Read online

Platinum-palladium/carbon nanjtubes (CNT) carbon nanocomposites were synthesized by chemical reduction of ions in water-organic solutions of reverse microemulsions. Physico-chemical characteristics of the nanocomposites were studied by atomic force microscopy, transmission electron microscopy, photon-correlation spectroscopy, X-ray phase analysis and chronopotentiometry. It was found that the smallest platinum-palladium nanoparticles size is observed when the metal ratio is 3:1 and the water pool size is minimal (ω = 1.5). Testing of catalytic activity in the oxidation of formic acid showed that the platinum-palladium/CNT nanocomposites showed higher corrosion resistance than nanocomposites with pure palladium.

Keywords