Results in Optics (May 2024)
Influence of Ni2+ ions on the physical, structural, elastic, optical, and thermal aspects of oxy fluoro borate glasses mixed with sesquioxide ions (Al3+/Y3+/Sb3+)
Abstract
Oxy Fluoro Borate (OFB) Glasses mixed with Sesquioxide ions (Al3+/Y3+/Sb3+) were synthesized using the traditional melt quenching technique. The properties of the structure of the glasses prepared are investigated by SEM, EDS and XRD methods. Variations in properties like density in glasses allow Nickel/Aluminium/Antimony/Yttrium ions to go through the borate glass matrix with an increase in respective dopant mole fraction. The decrease in the values of different elastic constants with B-O-Ni/Al/Sb/Y bonds and alsoby the function of NiO/Al2O3/Sb2O3/Y2O3 as a modifier and converting a portion of BO3 tetrahedral units into BO4octahedral units indicates the depolymerization in the glass matrix. The I.R. spectra and FTIR spectra show an increment in the occupation of cations Ni2+, Y3+, Sb3+ and Al3+ ions in the octahedral positions of the glass matrix with an enhancement in their molefraction. Creation of NBOs owing to the transformation of BO3 to BO4 units is greater in Al3+ and the smallest in Y3+ with an increment in the sesquioxide concentration at a 1.00 mol% NiO concentration. The dominance of the nickel ions octahedral occupancy in the glasses prepared is revealed by the optical absorption spectra, which may be because of the ligand fields produced by various ions of sesquioxides present within the glass matrix creating NBO and many trapped electrons at the donor centers. Photoluminescence spectra of the prepared glasses show the octahedral occupation of the Ni2+ ions that is indicated by the transitions 3A2g(F) ↔ 3T1g(P) and 3T1g(P) → 3T2g(F). The synthesized glasses exhibit effective luminescence by Nickel ions, and the AlNi and NiAl glass series exhibit superior luminescence properties owing to their highest emission cross-sections compared with the other series of prepared glasses.
