Visible Light Induced Nano-Photocatalysis Trimetallic Cu_0.5Zn_0.5-Fe: Synthesis, Characterization and Application as Alcohols Oxidation Catalyst

Abstract

Here, we report a visible light-induced-trimetallic catalyst (Cu0.5Zn0.5Fe2O4) prepared through green synthesis using Tilia plant extract. These nanomaterials were characterized for structural and morphological studies using powder x-ray diffraction (P-XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The spinel crystalline material was ~34 nm. In benign reaction conditions, the prepared photocatalyst oxidized various benzylic alcohols with excellent yield and selectivity toward aldehyde with 99% and 98%; respectively. Aromatic and aliphatic alcohols (such as furfuryl alcohol and 1-octanol) were photo-catalytically oxidized using Cu0.5Zn0.5Fe2O4, LED light, H2O2 as oxidant, 2 h reaction time and ambient temperature. The advantages of the catalyst were found in terms of reduced catalyst loading, activating catalyst using visible light in mild conditions, high conversion of the starting material and the recyclability up to 5 times without loss of the selectivity. Thus, our study offers a potential pathway for the photocatalytic nanomaterial, which will contribute to the advancement of photocatalysis studies.

Keywords

• trimetallic
• nanoparticles
• iron oxide
• photocatalytic
• magnetic
• alcohol