Journal of the Serbian Chemical Society (Jan 2012)

Catalyst materials based on plasma-processed alumina nanopowder

  • Dubencovs Konstantins,
  • Sproge Elina,
  • Cvetkovs Antons,
  • Chornaja Svetlana,
  • Serga Vera,
  • Kulikova Lidija,
  • Palcevskis Eriks

DOI
https://doi.org/10.2298/JSC121116147P
Journal volume & issue
Vol. 77, no. 12
pp. 1799 – 1806

Abstract

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A platinum catalyst for glycerol oxidation by molecular oxygen has been developed applying the extractive-pyrolytic method and using, as a support, a fine alumina powder with an average particle size of 30-60 nm processed by plasma technology. The extractive-pyrolytic method (EPM) allows affixing small amounts of catalytic metals (1-5%) with the particle size ranging from several nanometers to several tens of nanometers onto the surface of the support. The prepared material - 4.8 wt. % platinum on nano-sized alumina - can be used as a catalyst for glycerol oxidation by oxygen with conversion up to 84%, in order to produce some organic acids (glyceric and lactic acid) with a selectivity of about 60%.

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