Complexation of a novel tetracationic cryptand with some guests and theoretical modeling(新型4价离子型穴醚与一些客体的络合及理论模拟)

Affiliations

ZHOUQi-zhong(周其忠): 1. Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江　台州　317000)
ZHONGAi-guo(钟爱国): 1. Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江　台州　317000)
CHENHua-qi(陈华奇): 1. Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江　台州　317000)
JIANGHua-jiang(蒋华江): 1. Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江　台州　317000)
CHENRen-er(陈仁尔): 1. Department of Chemistry, Taizhou University, Taizhou 317000, Zhejiang Province, China( 1.台州学院化学系，浙江　台州　317000)
GUHai-ning(顾海宁): 2. Department of Chemistry, Zhejiang University, Hangzhou 310028, China( 2.浙江大学化学系，浙江　杭州　310028)

Abstract

用冠醚与类双百草枯合成了新型的4价离子型穴醚，并且初步研究了它与3个客体的络合.4价离子型穴醚与百草枯的络合作用明显.4价离子型穴醚对3个客体有选择性识别作用.分子力学模拟结果也支持了以上结论.

ISSN: 1008-9497 (Print)
Publisher: Zhejiang University Press
Country of publisher: China
LCC subjects: Science: Mathematics: Instruments and machines: Electronic computers. Computer science; Science: Physics
Website: https://www.zjujournals.com/sci/EN/1008-9497/home.shtml