Cellulose nanocrystals-microfibrils biocomposite with improved membrane performance

Abstract

This study investigates eco-friendly membrane biocomposites derived from biomass, utilizing cellulose microfibrils (CMF) as the main membrane material. Cellulose nanocrystals (CNC), isolated from rice husk, were added as reinforcing fillers in CMF flat sheet membranes. CNC with concentrations of 0%, 10%, 20%, and 30% were employed. Scanning electron microscopy images revealed that CNC influenced the surface profile and the pore structure of the membranes, reducing the porosity by 23%. The empty areas formed by CMF interaction were effectively filled by CNC. This modified membrane resulted in an increase in NaCl rejection of up to 16%. Dynamic water contact angle demonstrated the role of CNC in enhancing permeability, with a shorter spreading time of 13 min. It was also confirmed by the highest flux of 351 L/m − 2h−1 under pure water flux conditions. Mechanical properties were significantly improved, with a 125% increase in tensile strength and a modulus of 329 MPa. The distribution of CNC within the membranes filled pores and enhanced CMF interaction, facilitated by abundant hydroxyl groups in CNC. Overall, this study highlights the potential of eco-friendly membrane biocomposites derived from biomass, offering valuable insights for the development of sustainable and efficient membrane materials.

Keywords

• Cellulose nanocrystals
• Cellulose microfibrils
• Biomass
• Biocomposite
• Membrane