Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides

Abstract

Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.

Keywords

• Carbohydrates
• C-glycosides
• carbocycles
• rearrangements