Nature Communications (Aug 2019)

Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks

  • Simon Krause,
  • Jack D. Evans,
  • Volodymyr Bon,
  • Irena Senkovska,
  • Paul Iacomi,
  • Felicitas Kolbe,
  • Sebastian Ehrling,
  • Erik Troschke,
  • Jürgen Getzschmann,
  • Daniel M. Többens,
  • Alexandra Franz,
  • Dirk Wallacher,
  • Pascal G. Yot,
  • Guillaume Maurin,
  • Eike Brunner,
  • Philip L. Llewellyn,
  • François-Xavier Coudert,
  • Stefan Kaskel

DOI
https://doi.org/10.1038/s41467-019-11565-3
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 12

Abstract

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Porous framework material DUT-49 was recently demonstrated to exhibit a unique counterintuitive negative gas adsorption (NGA) behaviour. Here the authors identify framework DUT-50 as an additional pressure amplifying material that features distinct NGA transitions, and suggest structural design criteria to access other such materials.