Nature Communications (Aug 2019)
Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
- Simon Krause,
- Jack D. Evans,
- Volodymyr Bon,
- Irena Senkovska,
- Paul Iacomi,
- Felicitas Kolbe,
- Sebastian Ehrling,
- Erik Troschke,
- Jürgen Getzschmann,
- Daniel M. Többens,
- Alexandra Franz,
- Dirk Wallacher,
- Pascal G. Yot,
- Guillaume Maurin,
- Eike Brunner,
- Philip L. Llewellyn,
- François-Xavier Coudert,
- Stefan Kaskel
Affiliations
- Simon Krause
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Jack D. Evans
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Volodymyr Bon
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Irena Senkovska
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Paul Iacomi
- Aix-Marseille Univ., CNRS, MADIREL (UMR 7246)
- Felicitas Kolbe
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Sebastian Ehrling
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Erik Troschke
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Jürgen Getzschmann
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Daniel M. Többens
- Helmholtz-Zentrum Berlin für Materialien und Energie
- Alexandra Franz
- Helmholtz-Zentrum Berlin für Materialien und Energie
- Dirk Wallacher
- Helmholtz-Zentrum Berlin für Materialien und Energie
- Pascal G. Yot
- Institut Charles Gerhardt Montpellier UMR 5253 Univ. Montpellier CNRS UM ENSCM, Université de Montpellier, Place Eugène Bataillon
- Guillaume Maurin
- Institut Charles Gerhardt Montpellier UMR 5253 Univ. Montpellier CNRS UM ENSCM, Université de Montpellier, Place Eugène Bataillon
- Eike Brunner
- Faculty of Chemistry and Food Chemistry, TU Dresden
- Philip L. Llewellyn
- Aix-Marseille Univ., CNRS, MADIREL (UMR 7246)
- François-Xavier Coudert
- Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie, Paris
- Stefan Kaskel
- Faculty of Chemistry and Food Chemistry, TU Dresden
- DOI
- https://doi.org/10.1038/s41467-019-11565-3
- Journal volume & issue
-
Vol. 10,
no. 1
pp. 1 – 12
Abstract
Porous framework material DUT-49 was recently demonstrated to exhibit a unique counterintuitive negative gas adsorption (NGA) behaviour. Here the authors identify framework DUT-50 as an additional pressure amplifying material that features distinct NGA transitions, and suggest structural design criteria to access other such materials.