Energy Reports (Nov 2021)

Energy-efficient synthesis of crude phenol separation process using advanced heat integrated technology

  • Pingqiang Gao,
  • Yan Zhang,
  • Hao Chen

Journal volume & issue
Vol. 7
pp. 1888 – 1902

Abstract

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The current crude phenol separation process is featured by the conventional distillation columns and its close boiling range between the components significantly increases the energy consumption. Compared to the conventional heat integrated technology, the advanced heat integrated technology has more or less advantage of simple structure, higher energy efficiency and economic benefit in some specific separation schemes but is lack of the application in process transformation. It has the potential to be a high-energy-efficient way to improve the energy efficiency of the crude phenol separation process. An improved middle vapor recompression distillation column (IMVRC) was proposed on the basis of the conventional middle vapor recompression distillation column (MVRC), with more consideration of operating pressure set and separated stage. The vapor recompression distillation column (VRC) and MVRC are used as the competitive configurations to estimate the performance of IMVRC for separating three different boiling range mixtures. Besides, the crude phenol process is established as two steam-driven and three electrical-driven processes with the conventional and advanced heat integrated technologies used. Furthermore, the flexibility of IMVRC for the process design is investigated and the extended structure of IMVRC (E-IMVRC) for the crude phenol separation process is achieved. The results show the IMVRC has the preferable energy and total annual cost (TAC) benefits in all the different boiling range mixtures. And the different separated stage makes the distinct structure of IMVRC with different cooling and heating duty arrangement, which benefits the potential heat integrated flexibility in the process design. Consequently, the electrical-driven processes have the significant TAC saving than the steam-driven processes. Moreover, the E-IMVRC performs best in all the 4E analysis.

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