Remote Measurements of Industrial CO₂ Emissions Using a Ground-Based Differential Absorption Lidar in the 2 µm Wavelength Region

Abstract

Carbon dioxide (CO2) is a known greenhouse gas and one of the largest contributors to global warming in the Earth’s atmosphere. The remote detection and measurement of CO2 from industrial emissions are not routinely carried out and are typically calculated from the fuel combusted or measured directly within ducted vents. However, these methods are not applicable for the quantification of fugitive emissions of CO2. This work presents the results of remote measurement of CO2 emissions using the differential absorption lidar (DIAL) technique at a wavelength of ~2 µm. The results from the DIAL measurements compare well with simultaneous in-stack measurements, these datasets were plotted against each other and can be described by a linear regression of y (t/h) = 1.04 x − 0.02, suggesting any bias in the DIAL data is likely small. Moreover, using the definition outlined in EN 15267-3 a lower detection limit of 0.12 t/h was estimated for the 2 µm wavelength DIAL data, this is three orders of magnitude lower than the corresponding CO2 detection limit measured by NPL in the 1.5 µm wavelength region. Thus, this paper demonstrates the feasibility of high-resolution, ground-based DIAL measurements for quantifying industrial CO2 emissions.

Keywords

• DIAL
• laser spectroscopy
• carbon dioxide
• industrial emissions
• GHG
• CCUS