Design and construction of a three‐dimensional electrode with biomass‐derived carbon current collector and water‐soluble binder for high‐sulfur‐loading lithium‐sulfur batteries
Pengfei Wang,
Zhe Gong,
Ke Ye,
Vipin Kumar,
Kai Zhu,
Linna Sha,
Jun Yan,
Jinling Yin,
Kui Cheng,
Guiling Wang,
Dianxue Cao
Affiliations
Pengfei Wang
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Zhe Gong
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Ke Ye
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Vipin Kumar
Centre For Energy Studies Indian Institute of Technology Delhi New Delhi India
Kai Zhu
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Linna Sha
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Jun Yan
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Jinling Yin
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Kui Cheng
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Guiling Wang
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Dianxue Cao
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering Harbin Engineering University Harbin China
Abstract Lithium‐sulfur batteries attract lots of attention due to their high specific capacity, low cost, and environmental friendliness. However, the low sulfur utilization and short cycle life extremely hinder their application. Herein, we design and fabricate a three‐dimensional electrode by a simple filtration method to achieve a high‐sulfur loading. Biomass porous carbon is employed as a current collector, which not only enhances the electronic transport but also effectively limits the volume expansion of the active material. Meanwhile, an optimized carboxymethyl cellulose binder is chosen. The chemical bonding restricts the shuttle effect, leading to improved electrochemical performance. Under the ultrahigh sulfur load of 28 mg/cm2, the high capacity of 18 mAh/cm2 is still maintained, and stable cycling performance is obtained. This study demonstrates a viable strategy to develop promising lithium‐sulfur batteries with a three‐dimensional electrode, which promotes sulfur loading and electrochemical performance.
