Ultrafiltration study of the polysulfone membrane modified with branched polyethyleneimine

Abstract

This work discussed the fabrication of polysulfone (PSF) ultrafiltration membranes with hydrophilic behaviour by adding branched polyethyleneimine (PEI) as an additive. By directly blending the base polymer and the additive in the organic solvent, the casting solution is prepared. An asymmetric ultrafiltration membrane was fabricated by the phase inversion method. The presence of PEI was confirmed by comparing the IR spectra of the plain PSF membrane and the modified PSF membrane. A scanning electron microscope was used for the comparison of morphological changes in plain and modified membranes. The membrane was characterised with respect to bovine serum albumin (BSA) adsorption, pure water flux, permeability, compaction factor, humic acid (HA) rejection, and water uptake. The fouling resistance behaviour is prompted due to the presence of hydrophilic PEI chains in the membrane. As a result, pure water flux and flux recovery ratio increased from 28.84 to 326.54 L/m2h and from 0.526 to 0.954 L/m2hkPa for the modified membrane with respect to the plain membrane, respectively. HIGHLIGHTS Polysulfone (PSF) ultrafiltration membranes with hydrophilic behaviour by adding the polyethyleneimine branched (PEI) as an additive were fabricated.; High percentage of HA rejection was achieved with good antifouling properties.; BSA adsorption also decreased with respect to the weight percentage of PEI.;

Keywords

• fouling
• hydrophilic
• membrane
• polysulfone