Management of γ-Alumina with High-Efficient {111} External Surfaces for HDS Reactions

Abstract

A series of γ-alumina samples with different exposure ratio of {111} facet were synthesized by an efficient hydrothermal method via adjusting the pH value of the gel precursor. The nanorod alumina supported catalyst with the highest exposure of {111} facet exhibited the best hydrodesulfurization (HDS) activities of both thiophene and dibenzothiophene (DBT). Characterization of the sulfided NiMo/Al2O3 catalyst with preferential exposure of {111} facet showed that the MoS2 nano slabs were inclined to distribute in the direction along the edges of alumina nanocrystal in reduced stacking layers. The selective exposure of {111} facet played a decisive role in obtaining alumina-supported HDS catalysts with improved intrinsic activity. This work helps to better understand the relationship between catalytic properties and varied support surfaces, which demonstrate a proper design of the catalyst support morphology on the facet-level.

Keywords

• Thiophene hydrodesulfurization
• dibenzothiophene
• alumina nanorods
• {111} facet