Sustainable Fully Printed UV Sensors on Cork Using Zinc Oxide/Ethylcellulose Inks
Joana Figueira,
Cristina Gaspar,
José Tiago Carvalho,
Joana Loureiro,
Elvira Fortunato,
Rodrigo Martins,
Luís Pereira
Affiliations
Joana Figueira
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Cristina Gaspar
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
José Tiago Carvalho
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Joana Loureiro
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Elvira Fortunato
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Rodrigo Martins
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Luís Pereira
i3N/CENIMAT, Department of Materials Science, NOVA School of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica, Portugal
Low-cost and large-scale production techniques for flexible electronics have evolved greatly in recent years, having great impact in applications such as wearable technology and the internet of things. In this work, we demonstrate fully screen-printed UV photodetectors, successfully fabricated at a low temperature on a cork substrate, using as the active layer a mixture of zinc oxide nanoparticles and ethylcellulose. The photoresponse under irradiation with a UV lamp with peak emission at 302 nm exhibited a quasi-quadratic behavior directly proportional to the applied voltage, with a photocurrent of about 5.5 and 20 μA when applying 1.5 V and 5 V, respectively. The dark current stayed below 150 nA, while the rise and falling times were, respectively, below 5 and 2 s for both applied voltages. The performance was stable over continuous operation and showed a degradation of only 9% after 100 bending cycles in a 45 mm radius test cylinder. These are promising results regarding the use of this type of sensor in wearable applications such as cork hats, bracelets, or bags.