Dual-Functional Lithiophilic/Sulfiphilic Binary-Metal Selenide Quantum Dots Toward High-Performance Li–S Full Batteries

Youzhang Huang; Liang Lin; Yinggan Zhang; Lie Liu; Baisheng Sa; Jie Lin; Laisen Wang; Dong-Liang Peng; Qingshui Xie

doi:10.1007/s40820-023-01037-1

Nano-Micro Letters (Mar 2023)

Dual-Functional Lithiophilic/Sulfiphilic Binary-Metal Selenide Quantum Dots Toward High-Performance Li–S Full Batteries

Youzhang Huang,
Liang Lin,
Yinggan Zhang,
Lie Liu,
Baisheng Sa,
Jie Lin,
Laisen Wang,
Dong-Liang Peng,
Qingshui Xie

Affiliations

Youzhang Huang: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Liang Lin: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Yinggan Zhang: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Lie Liu: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Baisheng Sa: College of Materials Science and Engineering, Multiscale Computational Materials Facility, Fuzhou University
Jie Lin: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Laisen Wang: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Dong-Liang Peng: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University
Qingshui Xie: State Key Lab for Physical Chemistry of Solid Surfaces, Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials, College of Materials, Xiamen University

DOI: https://doi.org/10.1007/s40820-023-01037-1
Journal volume & issue: Vol. 15, no. 1
pp. 1 – 18

Abstract

Read online

Highlights A bi-service host with lithiophilic/sulfiphilic Fe2CoSe4 quantum dots embedded in three-dimensional ordered nitrogen-doped carbon skeleton is elaborately developed for both the sulfur cathode and Li anode synchronously. The highly dispersed Fe2CoSe4 quantum dots can not only act as a redox accelerator to promote the bidirectional conversion of LiPSs but also regulate the uniform Li plating/stripping to mitigate the growth of Li dendrite. The assembled Li-S full batteries achieve excellent long-term cyclability and a remarkable areal capacity of 8.41 mAh cm2 at high sulfur loading of 8.50 mg cm2, and the pouch full battery also displays high capacity and cycling-stability at lean electrolyte condition.

Published in Nano-Micro Letters

ISSN: 2311-6706 (Print); 2150-5551 (Online)
Publisher: SpringerOpen
Country of publisher: Germany
LCC subjects: Technology
Website: http://www.springer.com/40820

About the journal

Abstract

Keywords