Li⁺ Separation from Multi-Ionic Mixtures by Nanofiltration Membranes: Experiments and Modeling

Abstract

Aqueous sources like salt lake brines and seawater are the most abundant source for lithium ions and might contribute to the growing demand for lithium for energy storage. By coupling with the increasingly relevant reverse osmosis systems, nanofiltration can provide a promising process alternative to conventional methods such as water evaporation and salt precipitation from ores or brines for this purpose. One possible model for nanofiltration is the solution-diffusion-electromigration model (SDEM). First, the model was parametrized by determining the permeances from simple electrolyte mixtures containing two salts. Then, the SDEM was used to predict the rejections of complex multi-electrolyte solutions that mimic seawater and reverse osmosis brine, without fitting additional parameters to experimental data of this complex mixture. This allowed predicting ion rejections satisfactorily. Negative rejections due to spontaneously generated electric fields in the membrane could also be qualitatively described. In summary, this SDEM modeling can provide an important contribution to the purification of Li+ from aqueous sources.

Keywords

• solution-diffusion-electromigration
• Mg²⁺/Li⁺ ratio
• electrolyte mixtures