Acta Crystallographica Section E (Jul 2013)

Bis(dicyanamido-κN)[tris(3-aminopropyl)amine-κ4N]nickel(II)

  • Jun Luo,
  • Xin-Rong Zhang,
  • Li-Juan Qiu,
  • Feng Yang,
  • Bao-Shu Liu

DOI
https://doi.org/10.1107/S1600536813015651
Journal volume & issue
Vol. 69, no. 7
pp. m385 – m386

Abstract

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In the title complex, [Ni(C2N3)2(C9H24N4)], the NiII atom is coordinated in a distorted octahedral geometry by one tris(3-aminopropyl)amine (trisapa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Intermolecular N—H...N hydrogen bonds involving the N atoms of the dca anions and the trisapa amine H atoms result in the formation of a three-dimensional network.