Investigation of Thermal Properties of Zr-Based Metallic Glass–Polymer Composite with the Addition of Silane
Adit Sharma,
Dmitry Muratov,
Mikhail Zadorozhnyy,
Andrey Stepashkin,
Andrey Bazlov,
Artem Korol,
Ruslan Sergiienko,
Victor Tcherdyntsev,
Vladislav Zadorozhnyy
Affiliations
Adit Sharma
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Dmitry Muratov
Scientific School “Chemistry and Technology of Polymer Materials”, Plekhanov Russian University of Economics, Stremyanny lane 36, 117997 Moscow, Russia
Mikhail Zadorozhnyy
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Andrey Stepashkin
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Andrey Bazlov
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Artem Korol
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Ruslan Sergiienko
Physico-Technological Institute of Metals and Alloys, National Academy of Sciences of Ukraine, 34/1 Vernadsky Ave., 03680 Kyiv, Ukraine
Victor Tcherdyntsev
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Vladislav Zadorozhnyy
Centre of Composite Materials, National University of Science and Technology “MISiS”, LeninskyProsp 4, 119049 Moscow, Russia
Composites based on Zr65Cu17.5Ni10Al7.5/PTFE (polytetrafluoroethylene) with silane were prepared by ball milling with subsequent thermal pressing. Silanization was performed in the alcoholic solution with metallic glass powder. Different composites, 30/70 and 50/50 with silane, were prepared. During ball milling, Zr2Cu and Zr2Ni intermetallic phases were formed. The Zr-based metallic glass had a large supercooled region, and the melting point of the 30/70 and 50/50 composites with silane was near to the melting point of PTFE. The 50/50 composite (silane) had the highest thermal conductivity compared to the 30/70 composite samples. The incorporation of silane in metallic glass/polymer was investigated by Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) analysis. Thermogravimetric analysis (TGA) showed the thermal stability of the composite samples up to 450–460 °C. It was also concluded that the 50/50 composite with silane has better thermal stability than the 30/70 composite with silane. The addition of silane in 30/70 and 50/50 composites increased the thermal conductivity compared to the composites without silane.
