Judd–Ofelt Analysis and Emission Properties of Dy³⁺ Ions in Borogermanate Glasses

Abstract

Borogermanate glasses singly doped with Dy3+ ions were synthesized and then studied using the absorption and luminescence spectra. Spectroscopic changes of Dy3+ ions have been examined for compositional-dependent glasses with various molar ratios GeO2:B2O3. In this work, several spectroscopic parameters of Dy3+ ions were obtained experimentally and compared to the calculated values from the Judd–Ofelt theory. Luminescence spectra measured for borogermanate glasses consist of blue, yellow and red bands, which correspond to 4F9/2 → 6H15/2, 4F9/2 → 6H13/2 and 4F9/2 → 6H11/2 transitions of Dy3+, respectively. Luminescence lifetimes for the 4F9/2 excited state are reduced, whereas the stimulated emission cross-sections for the most intense 4F9/2 → 6H13/2 yellow transition of Dy3+ increase with increasing GeO2 and decreasing B2O3 concentrations in glass-hosts. Quantum efficiency of the 4F9/2 (Dy3+) excited state is nearly independent on molar ratios GeO2:B2O3. Attractive spectroscopic properties related to the 4F9/2 → 6H13/2 transition of Dy3+ ions are found for borogermanate glasses implying their potential utility for yellow laser action and solid-state lighting technology.

Keywords

• borogermanate glasses
• Dy³⁺ ions
• absorption
• emission
• Judd–Ofelt analysis