Synthesis and structures of Cu-Cl-M adducts (M=Zn, Sn, Sb)

Kociok-Köhn Gabriele; Mahon Mary F.; Molloy Kieran C.; Sudlow Anna L.

doi:10.1515/mgmc-2013-0051

Main Group Metal Chemistry (Mar 2014)

Synthesis and structures of Cu-Cl-M adducts (M=Zn, Sn, Sb)

Kociok-Köhn Gabriele,
Mahon Mary F.,
Molloy Kieran C.,
Sudlow Anna L.

Affiliations

Kociok-Köhn Gabriele: Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
Mahon Mary F.: Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
Molloy Kieran C.: Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
Sudlow Anna L.: Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK

DOI: https://doi.org/10.1515/mgmc-2013-0051
Journal volume & issue: Vol. 37, no. 1-2
pp. 11 – 24

Abstract

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The novel bimetallic adducts [(Ph3P)2CuCl]2.ZnCl2 (1), {[(Me3P)CuCl]2.ZnCl2}n (2), [(Me3P)4Cu]+[(Me3P)2Cu(Cl)2ZnCl2]- (3), (Ph3P)2CuCl.SnCl2 (4), (Me3P)3CuSnCl3 (5), [(Ph3P)2CuCl.SbCl3]2 (6) and (Ph3P)3CuCl.SbCl3 (7) have been synthesized from combinations of R3P, CuCl and one of ZnCl2, SnCl2 or SbCl3, and their structures were determined. [(Me3P)2Cu]+[HPMe3]2+[Sb2Cl9]3- (8) and [(Me3P)4Cu]+[(Me3P)2Sb2Cl7]- (9) have been isolated as minor by-products from the reaction of Me3P, CuCl and SbCl3, and their structures were also determined.

Published in Main Group Metal Chemistry

ISSN: 0792-1241 (Print); 2191-0219 (Online)
Publisher: De Gruyter
Country of publisher: Poland
LCC subjects: Science: Chemistry
Website: https://www.degruyter.com/view/j/mgmc

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