Green Synthesis and Catalysis (May 2024)

Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides

  • Yuting Chen,
  • Guanghui Lv,
  • Zhiyang Li,
  • Meiling Ye,
  • Tianle Huang,
  • Li Hai,
  • Yong Wu

Journal volume & issue
Vol. 5, no. 2
pp. 77 – 79

Abstract

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The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate scope and great functional group tolerance.

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