Synthesis and characterization of tris[butyl-(1-methyl-3phenyl-propyl)-dithiocarbamato]cobalt(III) seskvitoluen

Abstract

Anew bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmΦpdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmΦpdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III) [Co(bmΦpdtc)3]complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, 1H and 13C-NMR spectroscopy.

Keywords

• cobal(iii) complex
• dithiocarbamate
• bidentate ligand.